В журнале Inorganic Chemistry (IF=4,7) опубликована статья с участием сотрудников Лаборатории гетероциклических соединений: к.х.н., снс Е.А. Радюш и д.х.н. и зав.лабораторией, к.х.н. Н. А. Семенова:
Dichlorine-Containing Chlorothallate(III) (Me4N)3{[Tl2Cl9](Cl2)}: Crystal Structure and Thermal Stability
Nikita A. Korobeynikov, Andrey N. Usoltsev, Ekaterina A. Radiush, Nikolay A. Semenov, Maxim N. Sokolov, Sergey A. Adonin
Inorg. Chem. 2026, 65, 5, 2894–2901
Published: January 27, 2026
https://doi.org/10.1021/acs.inorgchem.5c05013
Abstract
The first example of a supramolecular complex of high-valent thallium(III)-containing “trapped” dichlorine, (Me4N)3{[Tl2Cl9](Cl2)} (1), has been prepared. 1 was characterized by X-ray single-crystal diffractometry, indicating the presence of the “trapped” dichlorine unit with prominent Cl···Cl noncovalent interactions. The complex demonstrates a relatively high thermal stability (up to 140 °C). Features of the Cl···Cl halogen contacts were examined by Raman spectroscopy.
