В журнале International Journal of Molecular Sciences (IF=5,6) опубликована статья с участием сотрудников Института: д.х.н. Е.С. Стоянова (внс, ЛМР) и И.В. Стояновой (инженер ЛМР):
Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
Evgenii S. Stoyanov and Irina V. Stoyanova
Int. J. Mol. Sci. 2023, 24(2), 1802;
Published: 11 Jan 2023
https://doi.org/10.3390/ijms24021802
(This article belongs to the Special Issue Structure, Energy and Dynamics of Molecular Interactions)
Abstract
It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research.
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