The organoboron compounds: their Lewis acidity and catalytic activity

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На сайте журнала Catalysis Reviews   (IF=10,9) опубликован обзор  с участием д.х.н. В.В. Бардина, ведущено научного сотрудника Лабортории галоидных соединений:

The organoboron compounds: their Lewis acidity and catalytic activity

Mikhail M. Shmakov, Sergey A. Prikhod’ko, Valentina N. Panchenko,  Maria N. Timofeeva, Vadim V. Bardin, Valentin N. Parmon and Nicolay Yu. Adonin

Catalysis Reviews, 2024,
Published online: 03 Apr 2024

https://doi.org/10.1080/01614940.2024.2334462

 

Abstract

lctr a 2334462 uf0001 oc

The review examines and summarizes methods for determining the Lewis acidity of organoboron compounds. Insights into the challenges and future development towards scales of Lewis acidity for boron Lewis acids based on the thermodynamic (global), spectral (effective) and intrinsic methods also are provided. The main challenges arising from the application of data on the Lewis acidity of organoboranes for an explanation of their catalytic behavior are discussed.

 


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